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Beilstein J. Org. Chem. 2019, 15, 727–732, doi:10.3762/bjoc.15.68
Graphical Abstract
Figure 1: (a) Isomerization of parent diazocine 1. Distances of carbon atoms para to the ethylene bridge were...
Figure 2: Synthesized target diazocines 4–7 for applications in responsive materials.
Scheme 1: Key reactions in diazocine synthesis.
Scheme 2: Syntheses of the functionalized diazocines 4–7. Reaction conditions: i) Isobutylene, sulfuric acid,...
Figure 3: UV–vis spectra of 3,3’-diaminodiazocine 2 (left), 3,3’-di(aminomethyl)diazocine 6a (center), and 3,...